Stopping a Bullet: The new superstrong fibre

Mechanical and industrial engineering assistant professor Marilyn Minus has developed a superstrong fiber that rivals the best in the industry. 

Credit: Mary Knox Merrill

In today's market for high performance fibers, used for applications such as bulletproof vests, manufacturers have only four options: Kevlar, Spectra, Dyneema, and Zylon.

Made from polymers such as polyethylene, these were the strongest synthetic fibers in the world—until recently.

Marilyn Minus, an assistant professor of engineering at Northeastern University, has developed a type of fiber that is stronger than the first three commercial products mentioned above, and—even in its first generation—closely approaches the strength of the fourth (Zylon).

Adding small amounts of carbon nanotubes—straight, cylindrical particles made entirely of carbon—to polymer fibers increases their strength marginally.

As a graduate student at the Georgia Institute of Technology five years ago, Minus figured that with a little more control, she might be able to turn those modest improvements into dramatic ones. She has spent the last four years at Northeastern proving her hunch.

In a paper recently released in the journal Macromolecular Materials and Engineering, Minus presented a tunable process for creating super-strong fibers that rival the industry's very best.

As with previous work, Minus' method integrates carbon nanotubes into the polymer fiber, but rather than serving as simply an added ingredient, the nanotubes now also perform an organizational role.

From carbon black powder to metallic particles, a variety of materials can guide the formation of specific crystal types in a process called nucleation. But before carbon nanotubes, Minus said, "we've never had a nucleating material so similar to polymers."

In the current research, Minus and her colleagues worked out the recipe and process for one particular polymer: polyvinyl alcohol. "But we can do this with other polymers and we are doing it," she said.

With funding from a new grant from the US Defense Advanced Research Projects Agency (DARPA), Minus will now work out the method for a polymer called polyacrylonitrle (PAN).

This is the dominant material used to form carbon fibers, which are of particular interest in lightweight composite materials such as those used in the Boeing 787 airliner.

With the more organized structure afforded by Minus' method, this material could see a vast increase in its already great performance.